Manchester United will take on two-time runners-up Paris Saint-Germain for a place in the Women’s Champions League group stage.
United will host the first leg of the second qualifying round tie on October 10 or 11.
The second leg will see Marc Skinner’s side play in France on October 18 or 19.
United have secured a European spot for the first time with their second-place finish in the Women’s Super League last season.
The round also includes Scottish champions Glasgow City taking on Norway’s SK Brann.
Chelsea already have a place in the group stage after winning the WSL last season.
Arsenal – who came third in the WSL in 2022-23 and, like Chelsea, were Champions League semi-finalists – were eliminated in the first qualifying round last week, beaten on penalties by Paris FC after a 3-3 draw.